Before You Begin
Question #44100
The Question
A rigid container of total volume is divided into two compartments, A and B, by a freely movable, strictly solvent-permeable semi-permeable membrane. Compartment A initially has a volume of and contains an aqueous solution comprising of and of . Compartment B initially has a volume of and contains an aqueous solution of of sucrose (a non-electrolyte). For the sparingly soluble salt , the solubility product is at . Assume ideal behavior for all solutions, complete dissociation of strong electrolytes, and that the volume of the solid precipitate is negligible. When the system reaches thermodynamic equilibrium at , what is the mass of precipitated? (Given: Molar mass of )
Options
- A.
12.0 g
- B.
15.0 g
- C.
18.0 g
- D.
30.0 g
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Numerical_Precision
Improve calculation stamina and avoid rounding errors in high-stakes competitive examinations.
Concepts Behind This Question
Solubility Product (Ksp) vs. Ionic Product (Qsp)|Isotonic, Hypertonic, Hypotonic
Why This Question Is Tricky
Common Mistakes
This problem tests the coupling of colligative properties with ionic equilibrium.
The 'Hidden Variable' is the dynamic loss of osmolarity due to precipitation.
Students commonly fall into the trap of calculating the final volume based solely on the initial moles of solute (setting to get ), completely forgetting that as precipitates, it removes osmotically active particles from the solution.
This shifts the osmotic equilibrium further, leading to a coupled state.
Ignoring this dynamic loss yields , leading to the trap answer of 12.0 g.
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Equilibrium - Class 11 Part 1 |
| Concept | Solubility Product (Ksp) vs. Ionic Product (Qsp) |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |