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Question #44102
The Question
An aqueous solution is prepared at by mixing of and of in a perfectly clean, dust-free container. For , at . The homogeneous nucleation rate (nuclei ) is given by , where the pre-exponential factor and the critical free energy of nucleation .
Given and , what is the concentration of remaining in the solution after ?
Options
- A.
- B.
- C.
- D.
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Mechanism_Trap
Don't get tricked by the process! Learn the mechanical traps used in competitive exam questions.
Concepts Behind This Question
Solubility Product (Ksp) vs. Ionic Product (Qsp)|Activation Energy Trap
Why This Question Is Tricky
Common Mistakes
This question tests the critical distinction between thermodynamic spontaneity () and kinetic feasibility (nucleation kinetics).
Students typically assume that precipitation is instantaneous once exceeds .
However, the formation of a solid phase requires overcoming a high activation energy barrier () for homogeneous nucleation.
By calculating the actual number of nuclei formed, the student must recognize that the solution is trapped in a metastable supersaturated state (Ostwald's Rule of Stages), meaning no precipitate forms within the experimental timeframe.
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Equilibrium - Class 11 Part 1 |
| Concept | Solubility Product (Ksp) vs. Ionic Product (Qsp) |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |