Before You Begin
Question #44127
The Question
Consider the following species at standard conditions: Tribromooctoxide (\ce{Br3O8}), Tetrathionate ion (\ce{S4O6^{2-}}), and Carbon suboxide (\ce{C3O2}). Let and be the actual oxidation state of an individual central atom in the homonuclear chains of \ce{Br3O8}, \ce{S4O6^{2-}}, and \ce{C3O2}, respectively. Let and be the actual oxidation state of an individual terminal atom in the homonuclear chains of the same respective species. Calculate the value of .
Options
- A.
52
- B.
66
- C.
84
- D.
17
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Mechanism_Trap
Don't get tricked by the process! Learn the mechanical traps used in competitive exam questions.
Concepts Behind This Question
Oxidation State Extremes|Average vs. Actual Oxidation State|Bond Angle Variations
Why This Question Is Tricky
Common Mistakes
This question targets the 'Average vs.
Actual Oxidation State' trap.
Students frequently rely on the arithmetic mean formula (e.g., +16/3 for Br in Br3O8 or +2.5 for S in S4O6^2-) without considering the structural reality of homonuclear bonds.
By asking for the specific oxidation states of central vs. terminal atoms, the problem forces the student to draw the correct Lewis structures and assign formal oxidation states based on electronegativity differences, punishing those who assume delocalized or averaged electronic states.
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Redox Reactions - Class 11 Part 2 |
| Concept | Oxidation State Extremes |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |