Before You Begin
Question #44793
The Question
Consider the complex consecutive first-order reaction sequence occurring in a closed vessel at :
\ce{A(g) ->[k_1] I(g) ->[k_2] P(g)}
The Arrhenius parameters for the two steps are such that their pre-exponential factors are equal (), and the difference in their activation energies is .
A student attempts to apply the Steady-State Approximation (SSA) to the intermediate . However, recognizing the 'induction period' before SSA becomes strictly valid, the student measures the instantaneous rate of formation of product at the exact moment , where the concentration of intermediate reaches its absolute maximum.
If is the instantaneous rate of formation of at , and is the initial instantaneous rate of disappearance of at , determine the exact ratio .
Options
- A.
- B.
- C.
- D.
Check Your Answer
Correct Answer
Step-by-Step Solution
Explanation
How the Examiner Thinks
Exception_Exposure
Learn to identify edge cases and boundary exceptions that JEE examiners hide in math problems.
Concepts Behind This Question
Instantaneous vs. Average Rate|Steady State Approximation
Why This Question Is Tricky
Common Mistakes
This problem tests the transient 'induction period' of a consecutive reaction before the Steady-State Approximation (SSA) is fully established.
Students often blindly apply SSA () from , which would incorrectly imply that the rate of product formation equals the initial rate of reactant consumption (leading to Option C: 1).
By asking for the rate exactly at the peak of the intermediate's concentration (), the problem forces the student to acknowledge that while is momentarily true, the reactant has already depleted during the induction period.
The hidden variable is the exact extent of reactant depletion () before the steady-state maximum is reached.
Quick Facts About This Question
Question Information
| Subject | Chemistry |
| Chapter | Chemical Kinetics - Class 12 |
| Concept | Instantaneous vs. Average Rate |
| Difficulty | 8 |
| Cognitive Load | 7 |
| Target Solve Time | 160 sec |
| Access | Free |