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Physics • Class 11

Thermal Properties of Matter - Class 11 Part 2

Master Thermal Properties & Heat Transfer through focused practice that strengthens conceptual understanding, problem-solving skills, and the ability to recognize common traps and misconceptions. Explore challenging questions designed to develop deeper reasoning and confident application of key ideas.

Overview

This chapter covers the concepts of heat, temperature, thermal expansion, heat transfer, and specific heat capacity. Understand the behavior of matter under varying thermal conditions and its applications.

Why This Chapter Matters

  • Thermal properties are crucial for understanding the behavior of materials and designing systems in engineering, environmental science, and technology. These concepts help explain natural phenomena and industrial processes.

Real-Life Applications

  • Designing thermal insulation systems for buildings and appliances.
  • Understanding the expansion of bridges and railroads due to temperature changes.
  • Analyzing heat transfer in industrial and environmental processes.

Skills You Will Learn

  • Calculating heat, temperature changes, and thermal expansion.
  • Understanding heat transfer mechanisms: conduction, convection, and radiation.
  • Applying the concepts of specific heat and thermal conductivity.

Core Concepts to Master

Celsius-Fahrenheit Calibration Errors

Account for non-zero lower fixed points in faulty thermometers; use linear interpolation (T-LFP)/(UFP-LFP) = constant.

Thermal Expansion of Area and Volume

Coefficients are not always exactly 2α and 3α for anisotropic solids; check for thermal stress implications.

Expansion of Cavities in Solids

Cavities expand exactly as if they were filled with the material of the solid; radius increases with temperature.

Thermal Stress in Constrained Rods

Calculate force F = Y A α ΔT; verify if the supports are rigid or yielding (spring-like).

Variation of Density with Temperature

Density ρ' = ρ / (1 + γΔT); watch for subtle errors in volume change approximation at high ΔT.

Specific Heat Capacity of Phase Mixtures

Account for latent heat versus sensible heat; ensure final state (solid, liquid, or gas) is correctly identified.

Calorimetry with Heat Loss

If system is not adiabatic, equate heat lost by hot bodies to heat gained by cold bodies plus surroundings.

Latent Heat and Volume Change

Work done during phase change is W = PΔV; critical for internal energy change calculations.

Thermal Conductivity in Series and Parallel

Equivalent conductivity Keq is weighted by length (series) or area (parallel); watch for heat flow direction.

Steady State Temperature Gradient

Temperature drop across a slab is proportional to thermal resistance; analogous to Ohm's Law (V=IR).

Newton’s Law of Cooling Limits

Valid only for small ΔT; use integration for large temperature differences or non-exponential cooling curves.

Stefan-Boltzmann Power Law

Net power radiated is σeA(T⁴ - Ts⁴); do not ignore the surrounding temperature Ts in high-level problems.

Wien’s Displacement Law

Focus on the peak wavelength shifting; peak intensity depends on T⁵, not just the wavelength position.

Emissivity and Absorptivity

Kirchhoff’s Law implies good emitters are good absorbers; emissivity 'e' is dimensionless and temperature-dependent.

Bimetallic Strip Curvature

Radius of curvature R = d / [(α2 - α1)ΔT]; assumes linear expansion and small deformation limits.

Concept Collisions Used by Examiners

Competitive examinations rarely assess concepts in isolation. Instead, examiners intentionally combine multiple concepts from this and related chapters to create higher-order questions that test conceptual reasoning, analytical thinking, and problem-solving ability. The concept collision patterns below represent the combinations most frequently used while designing questions for this chapter.

Celsius-Fahrenheit Calibration Errors
Adiabatic/Isothermal Processes via KTG
Celsius-Fahrenheit Calibration Errors
Damped Oscillation Equation
Celsius-Fahrenheit Calibration Errors
Dynamic Resistance (AC Resistance)
Celsius-Fahrenheit Calibration Errors
Equation of State for Mixtures
Celsius-Fahrenheit Calibration Errors
Thermal Stress in Constrained Rods
Thermal Expansion of Area and Volume
Capillary Rise Mechanics
Linear Regression Approximation
Thermal Expansion of Area and Volume
Effective Spring Constant
Interatomic Force Curve
Thermal Expansion of Area and Volume
Lens Silvering Logic
Binomial Approximation
Thermal Expansion of Area and Volume
Thermal Stress in Constrained Rods
Kinetic Friction Transition
Expansion of Cavities in Solids
Cavity Field Shielding
Integration
Expansion of Cavities in Solids
Polytropic Process
First Law of Thermodynamics
Expansion of Cavities in Solids
Superposition Principle
Small Angle Approximation
Expansion of Cavities in Solids
Torricelli’s Efflux Velocity
Differential Calculus
Expansion of Cavities in Solids
Young's Double Slit Geometry
Binomial Approximation
Thermal Stress in Constrained Rods
Effective Spring Constant
SHM Definition via Differential Equation
Thermal Stress in Constrained Rods
Interatomic Force Curve
Breaking Stress Concept
Thermal Stress in Constrained Rods
Stress vs. Strain Definition
Integration
Variation of Density with Temperature
Atmospheric Pressure Reference
Hydrostatics
Variation of Density with Temperature
Dielectric Constant (K) Shift
Electrostatics
Variation of Density with Temperature
Mechanical Energy Conservation
Archimedes Principle
Variation of Density with Temperature
Radioactive Decay Law Dynamics
Differential Equations
Specific Heat Capacity of Phase Mixtures
Energy Partitioning
Oscillations
Specific Heat Capacity of Phase Mixtures
Flux and Surface Geometry
Integration
Specific Heat Capacity of Phase Mixtures
Mechanical Energy Conservation
Work, Energy, and Power
Specific Heat Capacity of Phase Mixtures
Nuclear Fission Energy Balance
Specific Heat Capacity of Phase Mixtures
Temperature Coefficient (Alpha)
Integration
Calorimetry with Heat Loss
Adiabatic/Isothermal Processes via KTG
Integration
Calorimetry with Heat Loss
Archimedes' Buoyancy Dynamics
Integration
Calorimetry with Heat Loss
Eddy Currents Dissipation
Conservation of Energy
Calorimetry with Heat Loss
Entropy and Reversibility
Integration
Calorimetry with Heat Loss
Internal Resistance Variation
Current Electricity
Calorimetry with Heat Loss
Kirchhoff’s Loop Rule
Current Density Vector
Calorimetry with Heat Loss
Thermal Stress Calculation
Internal Energy Dependency
Calorimetry with Heat Loss
Transient Current in RL Circuit
Work, Energy, and Power
Calorimetry with Heat Loss
Work Done by Friction
Mechanical Energy Conservation
Latent Heat and Volume Change
Accelerated Frame Hydrostatics
Work-Energy Theorem Validity
Latent Heat and Volume Change
Adiabatic Process Constraint
Integration
Latent Heat and Volume Change
Collision Impulses
Vector Cross-Products
Latent Heat and Volume Change
Excess Pressure (Laplace Law)
Approximations (Binomial)
Latent Heat and Volume Change
Frame of Reference Inertial vs Non-Inertial
Integration
Latent Heat and Volume Change
Internal Energy Dependency
Integration
Latent Heat and Volume Change
Recoil of Atom
Energy Level Scaling
Latent Heat and Volume Change
Thermal Expansion of Area and Volume
Poisson's Ratio Limits
Latent Heat and Volume Change
Viscosity and Stokes' Law
Reynolds Number Transition
Thermal Conductivity in Series and Parallel
Steady State Temperature Gradient
Field due to Infinite Sheet
Thermal Conductivity in Series and Parallel
Transient Current in RL Circuit
Steady State Temperature Gradient
Steady State Temperature Gradient
Kirchhoff’s Loop Rule
Integration
Steady State Temperature Gradient
Stress vs. Strain Definition
Young's Modulus Sensitivity
Newton’s Law of Cooling Limits
Collision Impulses
Specific Heat Capacity of Phase Mixtures
Integration
Newton’s Law of Cooling Limits
Damped Oscillation Equation
Energy Partitioning
Phase Space Trajectory
Newton’s Law of Cooling Limits
Eddy Currents Dissipation
Molar Heat Capacity (Cv vs Cp)
Differential Equations
Stefan-Boltzmann Power Law
Gravitational Self-Energy
Integration
Stefan-Boltzmann Power Law
Power-Velocity Relationship
Vector Calculus
Stefan-Boltzmann Power Law
Radioactive Decay Law Dynamics
Differential Calculus
Stefan-Boltzmann Power Law
Thermal Stress in Constrained Rods
Binomial Approximation
Wien’s Displacement Law
Internal Energy Dependency
Adiabatic/Isothermal Processes
Wien’s Displacement Law
Magnetic Moment of Orbiting Electron
Vector Cross-Products
Wien’s Displacement Law
Maxwell-Boltzmann Distribution
Doppler Effect
Wien’s Displacement Law
Photon Neutrality
Wave-Particle Duality Constraint
Wien’s Displacement Law
Thermal Conductivity in Series and Parallel
Integration
Emissivity and Absorptivity
Lenz’s Law Energy Conservation
Vector Integration
Emissivity and Absorptivity
Magnetic Dipole Moment of Revolving Electron
Integration
Emissivity and Absorptivity
Newton’s Law of Cooling Limits
Virtual Object Trap
Emissivity and Absorptivity
Superposition Principle
Small Angle Approximation
Bimetallic Strip Curvature
Capillary Rise Mechanics
Vector Geometry
Bimetallic Strip Curvature
Effective Spring Constant
Integration
Bimetallic Strip Curvature
End Correction
Small Angle Approximation
Bimetallic Strip Curvature
Maxwell-Boltzmann Distribution
Approximation
Bimetallic Strip Curvature
Transient Current in RL Circuit
Differential Calculus

Exam Coverage

Understand how this chapter is tested across major competitive examinations.

JEE Advanced

India · Competitive Exam · Undergraduate

JEE Main

India · Competitive Exam · Undergraduate

BITSAT

India · Competitive Exam · Undergraduate

NEET-UG

India · Competitive Exam · Undergraduate

IISER Aptitude Test (IAT)

India · Competitive Exam · Undergraduate

NEST

India · Competitive Exam · Undergraduate

NSEP

India · Olympiad · High School

AP Physics 1

United States · Curriculum · Advanced Placement

AP Physics C: Mechanics

United States · Curriculum · Advanced Placement

AP Physics C: Electricity & Magnetism

United States · Curriculum · Advanced Placement

A-Level Physics

United Kingdom · Curriculum · Advanced Level

IB Physics HL

International · Curriculum · IB Diploma

Singapore A-Level Physics

Singapore · Curriculum · Advanced Level

Cambridge International A-Level Physics

International · Curriculum · Cambridge

International Physics Olympiad (IPhO)

International · Olympiad · International

Practice Questions

Strengthen your understanding by solving carefully selected questions from this chapter.

50 Questions
1

A faulty thermometer reads 5∘X5^\circ\text{X} at the melting point of ice and 95∘X95^\circ\text{X} at the boiling point of water at standard atmospheric pressure. A uniform metal rod is perfectly constrained between two rigid, immovable walls. The rod is heated, and the faulty thermometer records its initial and final temperatures as 14∘X14^\circ\text{X} and 86∘X86^\circ\text{X}, respectively. The rod has a constant coefficient of linear thermal expansion α=2×10−5 ∘C−1\alpha = 2 \times 10^{-5} \text{ } ^\circ\text{C}^{-1}. Its Young's modulus varies with the true Celsius temperature TT as Y(T)=Y0(1−βT)Y(T) = Y_0(1 - \beta T), where Y0=2×1011 N/m2Y_0 = 2 \times 10^{11} \text{ N/m}^2 and β=5×10−3 ∘C−1\beta = 5 \times 10^{-3} \text{ } ^\circ\text{C}^{-1}. Assuming the rod does not buckle, what is the magnitude of the thermal stress developed in the rod?

2

A thermistor has a temperature-dependent resistance given by R(T)=R0eβ/TR(T) = R_0 e^{\beta/T}, where TT is the absolute temperature in Kelvin. It is given that R0=10 ΩR_0 = 10\ \Omega and β=300ln⁡(3) K\beta = 300 \ln(3)\ \text{K}. The thermistor is connected in series with an inductor of inductance L=0.4 HL = 0.4\ \text{H} and an AC voltage source V(t)=100sin⁡(100t) VV(t) = 100 \sin(100t)\ \text{V}. The temperature is measured using a faulty linear scale ∘X^\circ X, on which the freezing and boiling points of water are 10∘X10^\circ X and 110∘X110^\circ X, respectively. In steady state, the thermistor reaches a constant operating temperature measured as 37∘X37^\circ X, while the surrounding environment is at 7∘X7^\circ X. Assuming Newton's law of cooling holds, what is the thermal dissipation constant KK of the thermistor?

3

An ideal diatomic gas (γ=1.4\gamma = 1.4) is initially at a temperature of 27∘C27^\circ\text{C}. It is compressed adiabatically to 132\frac{1}{32} of its original volume. A faulty thermometer is used to measure the temperature of the gas. This thermometer exhibits a linear response, reading 10∘X10^\circ\text{X} at the melting point of ice and 160∘X160^\circ\text{X} at the boiling point of water at standard atmospheric pressure. What is the final temperature of the gas as measured by this faulty thermometer? (Assume 0∘C=273 K0^\circ\text{C} = 273\text{ K})

4

A damped harmonic oscillator of mass m=0.2 kgm = 0.2\text{ kg} is submerged in a viscous fluid. The damping force is given by Fd=−bvF_d = -b v, where the damping coefficient bb depends on the absolute temperature TT (in Kelvin) of the fluid as b=αTb = \alpha T, with α=4×10−3 kg s−1 K−1\alpha = 4 \times 10^{-3}\text{ kg s}^{-1}\text{ K}^{-1}. The temperature of the fluid is measured using a faulty linear thermometer scale ∘X^\circ X. On this scale, the freezing point of water is 20∘X20^\circ X and the boiling point of water is 120∘X120^\circ X (at standard atmospheric pressure). During the experiment, the faulty thermometer reads 47∘X47^\circ X, and the damped angular frequency of the oscillator is measured to be ωd=4 rad s−1\omega_d = 4\text{ rad s}^{-1}. What is the undamped natural angular frequency ω0\omega_0 of the oscillator?

5

Two linear thermometers, A and B, have faulty calibrations. Thermometer A reads the freezing and boiling points of water as 10∘A10^\circ \text{A} and 130∘A130^\circ \text{A}, respectively. Thermometer B reads the same points as −20∘B-20^\circ \text{B} and 140∘B140^\circ \text{B}, respectively.

2 moles2 \text{ moles} of a monatomic ideal gas are initially at a temperature of 106∘A106^\circ \text{A}. 3 moles3 \text{ moles} of a diatomic ideal gas are initially at a temperature of −4∘B-4^\circ \text{B}. The two gases are mixed in a rigid, adiabatic container of fixed volume V=8.314 m3V = 8.314 \text{ m}^3.

Assuming no chemical reaction occurs, what is the final equilibrium pressure of the gas mixture? (Take the universal gas constant R=8.314 J mol−1K−1R = 8.314 \text{ J mol}^{-1} \text{K}^{-1} and absolute zero as −273∘C-273^\circ \text{C}.)

6

A thick uncharged conducting spherical shell has an inner radius R1R_1 and outer radius R2R_2. The spherical cavity (0≤r<R10 \le r < R_1) is completely filled with a uniformly charged compressible fluid of total charge QQ which always fills the cavity. The shell is made of a material whose coefficient of linear thermal expansion varies radially as α(r)=cr2\alpha(r) = \frac{c}{r^2} for R1≤r≤R2R_1 \le r \le R_2, where cc is a positive constant. The outer surface of the shell (r=R2r = R_2) is mechanically fixed such that it cannot move. The system is heated, increasing its temperature at a constant rate dTdt=β\frac{dT}{dt} = \beta. Assuming the radial displacement u(r)u(r) of the shell material is purely kinematic and governed by ∂u∂r=α(r)ΔT\frac{\partial u}{\partial r} = \alpha(r) \Delta T, find the rate of change of the electric field magnitude ∂E∂t\frac{\partial E}{\partial t} at a fixed distance rr (r<R1r < R_1) from the center at t=0t=0.

7

A cylindrical tank of constant cross-sectional area A1A_1 contains an ideal, incompressible liquid of density ρ\rho. At the bottom of the tank is a circular orifice made of a material with a coefficient of linear thermal expansion α\alpha. The tank walls have zero thermal expansion. Initially (t=0t=0), the liquid is at a height HH above the orifice, and the orifice has an area A0A_0 such that A1=2A0A_1 = 2A_0. The system is heated such that the temperature of the orifice increases at a constant rate dTdt=c\frac{dT}{dt} = c. Assuming the liquid density remains constant, find the initial rate of change of the efflux velocity of the liquid, dv2dt∣t=0\left. \frac{dv_2}{dt} \right|_{t=0}.

8

An unconstrained isotropic solid block contains a spherical cavity of radius RR centered at the origin (0,0,0)(0,0,0). The block is subjected to a steady-state temperature distribution T(x,y,z)=T0+βxT(x,y,z) = T_0 + \beta x, where T0T_0 and β\beta are positive constants. The rigid body motion of the block is constrained such that the theoretical displacement and rotation at the origin are zero. If α\alpha is the coefficient of linear thermal expansion of the material, what is the displacement vector of the point on the cavity boundary originally located at (0,R,0)(0, R, 0)? (Assume αβR≪1\alpha \beta R \ll 1).

9

A solid isotropic medium contains a spherical cavity of volume V0V_0. The cavity is filled with one mole of an ideal monatomic gas at an initial temperature T0T_0 and pressure P0P_0. The solid is heated quasi-statically. The cavity volume VV responds to both the temperature TT of the solid and the internal gas pressure PP according to the relation: V=V0[1+γ(T−T0)+P−P0K]V = V_0 \left[ 1 + \gamma (T - T_0) + \frac{P - P_0}{K} \right] where γ=52T0\gamma = \frac{5}{2T_0} is the volumetric thermal expansion coefficient and K=2P0K = 2P_0 is an effective elastic stiffness parameter. Assuming the gas and the solid are always in thermal equilibrium, what is the molar heat capacity of the gas at the beginning of the heating process (T=T0T = T_0)?

10

A Young's Double Slit Experiment (YDSE) apparatus is constructed entirely from a solid isotropic material with a coefficient of linear thermal expansion α\alpha. The slits are separated by a distance dd and the screen is rigidly attached at a distance DD from the slit plane. The apparatus is illuminated by a coherent light source of wavelength λ\lambda (which remains unaffected by the temperature of the apparatus). Initially, at temperature TT, the nthn^{\text{th}} order bright fringe is observed at a distance yny_n from the central maximum. If the entire apparatus is uniformly heated to a temperature T+ΔTT + \Delta T, what is the shift Δyn\Delta y_n in the position of the nthn^{\text{th}} order bright fringe? (Assume αΔT≪1\alpha \Delta T \ll 1 and retain leading-order terms in αΔT\alpha \Delta T)

11

A solid sphere of density ρ1\rho_1 at temperature T0T_0 is released from rest at the surface (y=0y=0) of a deep, non-viscous liquid column. The temperature of the liquid varies with depth yy as T(y)=T0−kyT(y) = T_0 - ky, where kk is a positive constant. The density of the liquid at T0T_0 is ρ2\rho_2, and it is given that ρ1=54ρ2\rho_1 = \frac{5}{4}\rho_2. The volume expansion coefficient of the liquid is γl=5α\gamma_l = 5\alpha and that of the sphere's material is γs=2α\gamma_s = 2\alpha. Assuming αky≪1\alpha k y \ll 1 so that higher-order terms can be neglected, what is the maximum depth HH reached by the sphere before it momentarily comes to rest?

12

A parallel plate capacitor of initial capacitance C0C_0 is connected to a constant voltage source VV. The space between the plates is completely filled with a non-polar liquid dielectric of initial dielectric constant K0K_0 at temperature T0T_0. The liquid has a volume expansion coefficient γ\gamma. The capacitor plates are held rigidly at a constant separation, and a small reservoir allows the liquid to expand out so the volume between the plates remains constant. Assuming the electric susceptibility of the liquid is directly proportional to its density, what is the magnitude of the change in the electrostatic energy stored in the capacitor when the temperature is increased by a small amount ΔT\Delta T? (Assume γΔT≪1\gamma \Delta T \ll 1)

13

A thermally insulated, solid radioactive sphere of initial radius R0R_0, mass mm, and specific heat capacity ss is placed in a vacuum. At t=0t=0, it contains N0N_0 active nuclei with a decay constant λ\lambda. Each decay releases energy QQ, which is completely absorbed by the sphere. The coefficient of linear thermal expansion of the sphere's material is α\alpha. Gamma photons emitted from the center of the sphere travel to the surface, undergoing attenuation according to I=I0e−τI = I_0 e^{-\tau}, where the optical depth τ=μR\tau = \mu R, and the linear attenuation coefficient μ\mu is directly proportional to the instantaneous density ρ\rho of the sphere. If the initial optical depth is τ0\tau_0, which of the following expressions represents the optical depth τ(t)\tau(t) at time tt? (Assume αΔT≪1\alpha \Delta T \ll 1).

14

A tall cylindrical tank of depth HH is completely filled with a liquid. The temperature of the liquid varies linearly with depth yy (measured downwards from the free surface) as T(y)=T0+cyT(y) = T_0 + c y, where T0T_0 is the surface temperature and cc is a positive constant. The density of the liquid varies with temperature as ρ(T)=ρ01+γ(T−T0)\rho(T) = \frac{\rho_0}{1 + \gamma(T - T_0)}, where ρ0\rho_0 is the density at T0T_0 and γ\gamma is the coefficient of volume expansion. Assuming acceleration due to gravity gg is constant and atmospheric pressure is P0P_0, the absolute pressure at the bottom of the tank is:

15

A block of ice of mass mm and density ρi\rho_i is released from rest from a height HH above the free surface of a liquid of density ρL\rho_L (ρL<ρi\rho_L < \rho_i). The liquid has mass MM and is contained in a perfectly insulated, rigid, closed cylindrical calorimeter. The space above the liquid is a vacuum. The initial depth of the liquid is dd. The ice block falls, sinks to the bottom of the calorimeter, and then melts completely. The initial temperature of the liquid is T0>0∘CT_0 > 0^\circ\mathrm{C} and the ice is at 0∘C0^\circ\mathrm{C}. The specific heat capacity of the liquid is sLs_L, the specific heat capacity of water is sws_w, and the latent heat of fusion of ice is LL. The density of water is ρw\rho_w. Assume the liquid and water are immiscible, and the cross-sectional area of the calorimeter is very large such that the depth of the melted water layer is negligible. Which of the following equations correctly represents the energy balance to find the final equilibrium temperature TfT_f of the mixture?

16

A nuclear micro-reactor powers a heating system by converting mass into energy. The rate of mass defect in the reactor varies with time as dmdt=λt\frac{dm}{dt} = \lambda t, where λ=1.4×10−13 kg/s2\lambda = 1.4 \times 10^{-13} \text{ kg/s}^2. The reactor operates from t=0t = 0 to t=10 st = 10 \text{ s}. The entire energy released is used to heat a mixture of two liquids, A and B, kept in a perfectly insulated container. Liquid A has a mass of 1 kg1 \text{ kg} and a temperature-dependent specific heat capacity sA(T)=αT2s_A(T) = \alpha T^2, where α=0.01 J kg−1K−3\alpha = 0.01 \text{ J kg}^{-1} \text{K}^{-3}. Liquid B has a mass of 2 kg2 \text{ kg} and a specific heat capacity sB(T)=αT2s_B(T) = \alpha T^2. If the initial temperature of the mixture is 100 K100 \text{ K}, find the final temperature of the mixture. (Take the speed of light c=3×108 m/sc = 3 \times 10^8 \text{ m/s}).

17

A cylindrical heating wire of initial resistance R0=1 ΩR_0 = 1 \text{ }\Omega at T0=300 KT_0 = 300 \text{ K} is submerged in an insulating vessel containing m=1 kgm = 1 \text{ kg} of a liquid with specific heat capacity s=4000 J kg−1K−1s = 4000 \text{ J kg}^{-1} \text{K}^{-1}. A constant voltage V=20 VV = 20 \text{ V} is applied across the wire. The temperature coefficient of resistivity of the wire is αρ=5×10−3 K−1\alpha_\rho = 5 \times 10^{-3} \text{ K}^{-1} and its coefficient of linear thermal expansion is αL=1×10−3 K−1\alpha_L = 1 \times 10^{-3} \text{ K}^{-1}. Assuming the heat capacity of the wire and the vessel are negligible, and no heat is lost to the surroundings, find the time tt required to heat the liquid to T=350 KT = 350 \text{ K}. (Use the approximation (1+x)n≈1+nx(1+x)^n \approx 1+nx for small xx).

18

A block of mass mm performs simple harmonic motion with amplitude AA and angular frequency ω\omega. The block acts as a heat source, generating thermal energy at an instantaneous rate P(t)=αU(t)P(t) = \alpha U(t), where U(t)U(t) is the instantaneous potential energy of the oscillator (taking U=0U=0 at the mean position) and α\alpha is a positive constant. This heat is supplied to a mixture of ice and water at 0∘C0^{\circ}\mathrm{C}. However, due to a thermal gating mechanism, heat is transferred to the mixture only when the block's displacement satisfies ∣x∣≥A/2|x| \ge A/2. If the latent heat of fusion of ice is LL, what is the mass of ice melted in one complete time period of the oscillation?

19

A spherical region of radius RR contains a weakly conducting ice-water mixture at 0∘C0^\circ\text{C} with uniform electrical conductivity σc\sigma_c and permittivity ϵ0\epsilon_0. An external mechanism maintains a steady, non-uniform volume charge density ρ(r)=ρ0rR\rho(r) = \rho_0 \frac{r}{R} throughout the sphere, where rr is the radial distance from the center. The resulting electric field causes Joule heating within the mixture. Assuming no heat is lost to the surroundings and the latent heat of fusion of ice is LfL_f, what is the mass of ice melted in time tt?

20

One mole of an ideal monatomic gas is enclosed in a cylinder with a movable piston. Starting at t=0t=0, the gas expands and does work on the piston at a constant rate W0W_0. Simultaneously, an internal electric heater supplies heat to the gas at a constant rate P0P_0 (where P0>W0P_0 > W_0). The cylinder walls are poorly insulated, resulting in a time-varying heat loss to the surroundings at a rate dQlossdt=αt\frac{dQ_{\text{loss}}}{dt} = \alpha t, where α\alpha is a positive constant. If the initial temperature of the gas is T0T_0, what is the maximum temperature reached by the gas during this process? (Here RR is the universal gas constant)

21

A lead bullet of mass mm, specific heat capacity cc, surface area AA, and emissivity ee is fired into a large target. The bullet enters the target at t=0t=0 with an initial velocity v0v_0 and experiences a constant retarding force FF. It comes to rest at time t=t0t = t_0. The initial temperature of the bullet and the constant temperature of the surroundings are both T0T_0. Assuming all the kinetic energy lost by the bullet is continuously converted into heat within the bullet, and it simultaneously radiates heat to the surroundings according to the Stefan-Boltzmann law, which of the following expressions gives the exact net temperature rise ΔT=T(t0)−T0\Delta T = T(t_0) - T_0 of the bullet? (Assume the bullet does not melt, T(t)T(t) is its temperature at time tt, and σ\sigma is the Stefan-Boltzmann constant).

22

A heating coil is submerged in a calorimeter containing a liquid. The coil is connected to a constant voltage source of V=20 VV = 20\ \text{V}. The resistance of the coil at the surrounding temperature Ts=25∘CT_s = 25^\circ\text{C} is R0=10 ΩR_0 = 10\ \Omega, and its temperature coefficient of resistance is α=0.05 ∘C−1\alpha = 0.05\ ^\circ\text{C}^{-1}. The calorimeter loses heat to the surroundings according to Newton's law of cooling, with a heat transfer coefficient k=1 W/∘Ck = 1\ \text{W/}^\circ\text{C}. Assuming the liquid is continuously stirred and maintains a uniform temperature, what is the steady-state temperature of the liquid?

23

Two solid blocks, A and B, have constant heat capacities CC and 2C2C, and initial temperatures 3T03T_0 and 2T02T_0 respectively. They are placed inside a massive evacuated chamber whose walls are maintained at a constant temperature T0T_0. The blocks are connected by a thermally conducting rod, allowing them to exchange heat with each other. Simultaneously, they lose heat to the chamber walls via non-linear Stefan-Boltzmann radiation. After a long time, the system reaches thermal equilibrium. What is the total change in entropy of the universe?

24

A heating coil of resistance RR and inductance LL is immersed in a calorimeter of heat capacity CC. At t=0t=0, the coil is connected to an ideal DC voltage source V0V_0. The calorimeter loses heat to the surroundings (at constant temperature T0T_0) at a rate k(T−T0)k(T - T_0), where TT is the instantaneous temperature of the calorimeter and kk is a positive constant. Assume the electrical time constant of the coil is exactly equal to the thermal time constant of the calorimeter, i.e., LR=Ck=τ\frac{L}{R} = \frac{C}{k} = \tau. If the initial temperature of the calorimeter is T0T_0, which of the following expressions correctly gives the temperature difference ΔT(t)=T(t)−T0\Delta T(t) = T(t) - T_0 at any time t>0t > 0?

25

A cylindrical vessel of cross-sectional area AA is placed in an elevator accelerating upwards with a constant acceleration aa. The vessel contains a mass mm of ice at 0∘C0^\circ\text{C}. A frictionless piston of mass MM rests on the ice, exposed to atmospheric pressure P0P_0. Heat is slowly supplied until the ice completely melts into water at 0∘C0^\circ\text{C}. Let LL be the increase in internal energy per unit mass during melting. The densities of ice and water are ρ1\rho_1 and ρ2\rho_2 respectively (ρ2>ρ1\rho_2 > \rho_1). What is the total heat QQ supplied to the system? (where gg is the acceleration due to gravity)

26

A microscopic system of initial rest mass MM is initially at rest. It undergoes a phase transition where its internal rest energy decreases by ΔU\Delta U. During the transition, the system expands by a volume ΔV\Delta V against a constant external pressure PP, doing mechanical work PΔVP\Delta V. The remaining available energy is emitted as a single photon, and the system recoils freely in vacuum. Which of the following gives the exact energy EγE_\gamma of the emitted photon? (Here cc is the speed of light in vacuum).

27

A thin spherical shell of radius rr and thickness tt (t≪rt \ll r) is completely filled with a liquid of mass MM and specific volume v0v_0 at its freezing temperature T0T_0. The shell material has Young's modulus YY, Poisson's ratio ν\nu, coefficient of linear thermal expansion α\alpha, and tensile yield stress σy\sigma_y. The system is slowly cooled. Upon freezing, the substance transforms into a solid with a larger specific volume vsv_s (let Δv=vs−v0>0\Delta v = v_s - v_0 > 0), releasing a latent heat of fusion LL. The expansion during freezing increases the internal pressure, which in turn lowers the freezing point via the Clausius-Clapeyron relation. Assuming the specific volumes of the liquid and solid phases are independent of pressure and temperature, what fraction ff of the liquid has frozen exactly when the shell begins to yield?

28

A spherical melting ice particle falls through a warm fluid. Due to uniform heat transfer, its radius rr decreases at a constant rate cc (i.e., drdt=−c\frac{dr}{dt} = -c). The particle always falls at its instantaneous terminal velocity. For large radii, the fluid flow is turbulent and the drag force is FD=k1r2v2F_D = k_1 r^2 v^2. For small radii, the flow is laminar and the drag force is FD=k2rvF_D = k_2 r v. The effective weight of the particle (gravity minus buoyancy) is given by Weff=k3r3W_{eff} = k_3 r^3. Assuming the transition between the drag regimes occurs abruptly when the terminal velocities predicted by both models are equal, what is the total distance HH the particle falls from an initial radius r0r_0 (where r0r_0 is in the turbulent regime) until it melts completely?

29

A small solid body of heat capacity C=20 J/KC = 20 \text{ J/K} is initially at a temperature T0=0∘CT_0 = 0^\circ\text{C}. It is connected to two large heat baths maintained at temperatures T1=100∘CT_1 = 100^\circ\text{C} and T2=0∘CT_2 = 0^\circ\text{C} through two distinct uniform rods of negligible heat capacity. The thermal resistances of the rods are R1=5 K/WR_1 = 5 \text{ K/W} (connected to T1T_1) and R2=20 K/WR_2 = 20 \text{ K/W} (connected to T2T_2). The connections are made simultaneously at t=0t = 0. Assuming no heat loss to the surroundings, what is the rate of heat flow from the 100∘C100^\circ\text{C} bath into the first rod at time t=80ln⁡2 st = 80 \ln 2 \text{ s}?

30

A spherical shell of inner radius aa and outer radius bb has a radially varying thermal conductivity given by k(r)=k0ark(r) = \frac{k_0 a}{r}, where k0k_0 is a positive constant. The inner surface at r=ar=a is maintained at temperature T1T_1 and the outer surface at r=br=b is maintained at temperature T2T_2 (T1>T2T_1 > T_2). In steady state, what is the temperature T(r)T(r) at a distance rr (a<r<ba < r < b) from the center?

31

A metallic sphere of mass mm is placed in a vacuum chamber maintained at absolute zero. It loses heat to the surroundings via a thermal link such that the rate of heat loss is Ploss=γTP_{loss} = \gamma T, where TT is the absolute temperature of the sphere and γ\gamma is a positive constant. Simultaneously, the sphere is subjected to a time-varying magnetic field that induces eddy currents. The power dissipated by these eddy currents is Peddy=βTP_{eddy} = \frac{\beta}{T}, where β\beta is a positive constant (this inverse dependence arises because the electrical resistivity of the metal is proportional to its absolute temperature, ρ∝T\rho \propto T). The specific heat capacity of the metal varies with temperature as s(T)=s0Ts(T) = s_0 T. If the sphere is initially at a temperature T0=2βγT_0 = 2\sqrt{\frac{\beta}{\gamma}}, what is the time tt required for it to cool down to Tf=2βγT_f = \sqrt{\frac{2\beta}{\gamma}}?

32

A thermally insulated vessel contains a mixture of water and 1 kg1 \text{ kg} of ice at 0∘C0^\circ\text{C}. The total mass of the vessel and its contents is 8 kg8 \text{ kg}. A projectile of mass 2 kg2 \text{ kg} traveling horizontally at 1000 m/s1000 \text{ m/s} strikes the vessel and embeds within it. The vessel is free to move on a frictionless horizontal surface. The collision is perfectly inelastic and generates heat internally within the vessel's thermal control volume. Assume all lost mechanical energy is instantaneously converted to heat. The total heat capacity of the system (vessel, mixture, and embedded projectile) is C=10,000 J/∘CC = 10,000 \text{ J/}^\circ\text{C} (assumed constant, excluding the latent heat of ice). The latent heat of fusion of ice is Lf=3.2×105 J/kgL_f = 3.2 \times 10^5 \text{ J/kg}. Immediately after the ice melts and thermal equilibrium is reached, the vessel's insulation is removed, exposing it to surroundings at 0∘C0^\circ\text{C}. The system then cools according to Newton's Law of Cooling with a cooling constant k=0.1 min−1k = 0.1 \text{ min}^{-1}. What is the temperature of the system 10ln⁡210 \ln 2 minutes after the insulation is removed?

33

A thermally isolated radioactive sample of initial mass m0m_0 and constant specific heat capacity cc is placed in a vacuum at absolute zero. The sample generates heat at a rate Pin(t)=P0e−λtP_{\text{in}}(t) = P_0 e^{-\lambda t} due to radioactive decay, and its mass decreases as m(t)=m0e−λtm(t) = m_0 e^{-\lambda t}. The sample loses energy via Stefan-Boltzmann radiation from its constant surface area AA, such that Pout(t)=σAT4P_{\text{out}}(t) = \sigma A T^4. The temperature TT of the sample is governed by the energy balance Pin(t)=Pout(t)+m(t)cdTdtP_{\text{in}}(t) = P_{\text{out}}(t) + m(t) c \frac{dT}{dt}. If the initial temperature of the sample is 0 K0\text{ K}, what is the value of d2Tdt2\frac{d^2T}{dt^2} at t=0t=0?

34

A solid spherical projectile of radius RR and emissivity ee moves at a constant high velocity vv through an atmosphere of constant density ρ\rho. The aerodynamic drag force acting on the projectile is given by Fd=12ρv2CdAcF_d = \frac{1}{2} \rho v^2 C_d A_c, where CdC_d is the drag coefficient and AcA_c is the effective cross-sectional area. Assume that the entire mechanical power dissipated by the drag force is absorbed by the projectile as internal thermal energy. If the projectile loses heat solely via thermal radiation to the surrounding environment (assumed to be at 0 K0\text{ K}), which of the following expressions represents the steady-state terminal temperature TT of the projectile? (Here, σ\sigma is the Stefan-Boltzmann constant).

35

A long cylindrical metal rod of initial radius r0r_0 and length L0L_0 is placed between two perfectly rigid, unyielding walls such that its length cannot change. Assume the rod is initially unstressed at 0 K0 \text{ K} and its material properties (emissivity ϵ\epsilon, coefficient of linear thermal expansion α\alpha, Young's modulus YY, and Poisson's ratio ν\nu) are temperature-independent. It is heated by a constant internal power source PP and radiates heat to the surrounding vacuum at 0 K0 \text{ K}. Neglecting heat loss from the flat ends and assuming αT≪1\alpha T \ll 1, what is the steady-state temperature TT of the rod to first order in α\alpha?

(Let T0=(Pϵσ2πr0L0)1/4T_0 = \left( \frac{P}{\epsilon \sigma 2\pi r_0 L_0} \right)^{1/4}, where σ\sigma is the Stefan-Boltzmann constant).

36

A spherical blackbody source of proper temperature T0T_0 moves directly towards a stationary observer with a constant velocity v=45cv = \frac{4}{5}c. In the rest frame of the source, the spectral radiance peaks at a wavelength λ0\lambda_0. The observer measures the incoming radiation. Let λobs\lambda_{obs} be the observed peak wavelength. Let IobsI_{obs} be the total observed radiance (energy per unit area per unit time per unit solid angle) integrated over all frequencies, and I0I_0 be the corresponding total proper radiance. Given that the quantity Iνν3\frac{I_\nu}{\nu^3} is Lorentz invariant (where IνI_\nu is the spectral radiance and ν\nu is the frequency), determine the values of λobsλ0\frac{\lambda_{obs}}{\lambda_0} and IobsI0\frac{I_{obs}}{I_0}.

37

An ideal diatomic gas is confined in a perfectly insulated cylinder with a movable piston. The gas is in thermal equilibrium and its radiation spectrum approximates that of a perfect blackbody. Initially, the internal energy of the gas is U0U_0 and its spectral emissive power peaks at a wavelength λ0\lambda_0. The gas undergoes an adiabatic expansion until the peak wavelength of its emitted radiation shifts to 2λ02\lambda_0. Which of the following represents the work done by the gas and the ratio of its final volume to initial volume (VfV0)\left(\frac{V_f}{V_0}\right), respectively?

38

A metallic block of heat capacity CC oscillates horizontally on a frictionless surface, attached to a spring. It passes through a uniform magnetic field, experiencing a damping force due to eddy currents. As a result, its mechanical energy decays as E(t)=E0e−t/τ1E(t) = E_0 e^{-t/\tau_1}, where E0E_0 is the initial energy. The work done against the damping force is entirely converted into heat within the block. Simultaneously, the block loses heat to the surroundings (at a constant temperature T0T_0) according to Newton's law of cooling, with a thermal time constant τ2\tau_2. If τ2=2τ1\tau_2 = 2\tau_1, and the block is initially at temperature T0T_0, what is the maximum temperature reached by the block?

39

A solid cylindrical rod of length LL, cross-sectional area AA, Young's modulus YY, and coefficient of linear thermal expansion α\alpha is rigidly clamped between two immovable walls at an ambient temperature T0T_0. It is heated via a calorimetry setup involving a hot liquid, reaching an initial uniform temperature T0+ΔT0T_0 + \Delta T_0. The combined heat capacity of the rod (excluding elastic energy) and the liquid is C0C_0. The system is then allowed to cool. The calorimeter loses heat to the surroundings at a rate dQdt=−k(T−T0)\frac{dQ}{dt} = -k(T - T_0), where kk is a positive constant and TT is the instantaneous temperature. Assuming the rod and liquid are always in thermal equilibrium, what is the time tt taken for the system to cool to T0+ΔT02T_0 + \frac{\Delta T_0}{2}?

40

A solid block of volume V0V_0 and density dd is completely submerged in a liquid and suspended by a vertical string. The liquid has an initial density ρ0\rho_0 (where ρ0<d\rho_0 < d), mass mm, specific heat capacity cc, and coefficient of volume expansion β\beta. The block's thermal expansion is negligible. At t=0t=0, a heater starts supplying heat to the liquid at a constant power PP. The liquid loses heat to the surroundings at a rate λ(T−T0)\lambda(T - T_0), where TT is the instantaneous temperature of the liquid, T0T_0 is the constant ambient temperature, and λ\lambda is a positive constant. Assuming uniform temperature in the liquid and β(T−T0)≪1\beta(T-T_0) \ll 1, which of the following expressions represents the tension in the string as a function of time tt?

41

A battery of electromotive force E=20 VE = 20 \text{ V} and internal resistance r=2 Ωr = 2 \ \Omega is connected across a heating coil placed in a calorimeter. The resistance of the coil varies with the temperature elevation ΔT\Delta T above the surroundings as R(ΔT)=R0(1+αΔT)R(\Delta T) = R_0(1 + \alpha \Delta T), where R0=2 ΩR_0 = 2 \ \Omega and α=0.05 K−1\alpha = 0.05 \text{ K}^{-1}. The calorimeter loses heat to the surroundings at a rate Ploss=kΔTP_{\text{loss}} = k \Delta T, where k=1516 W/Kk = \frac{15}{16} \text{ W/K}. Assuming the surroundings are at a constant temperature, what is the steady-state temperature elevation ΔT\Delta T of the calorimeter?

42

A perfectly insulated cylinder is fitted with a movable, frictionless piston. The cylinder contains nn moles of an ideal gas and a mass mm of ice. Initially, the system is in thermal equilibrium at temperature T0T_0 (the melting point of ice) and the gas pressure is P0P_0. The piston is slowly pushed inward by an external force until all the ice just melts. The gas and the ice-water mixture remain in thermal equilibrium throughout the process. Let LL be the specific enthalpy of fusion of ice (latent heat), and vi,vwv_i, v_w be the specific volumes of ice and water, respectively (assumed constant). Which of the following expressions gives the final pressure of the gas?

43

A projectile of mass mm moving with velocity v0v_0 strikes a block of ice of mass MM (initially at rest at 0∘C0^\circ\text{C}) and gets embedded in it. The collision takes place in an environment at constant atmospheric pressure P0P_0. The specific internal energy of fusion of ice (change in internal energy per unit mass during melting) is ufu_f. The densities of ice and water are ρi\rho_i and ρw\rho_w respectively (ρi<ρw\rho_i < \rho_w). Assuming no heat is exchanged with the surroundings and all the dissipated mechanical energy is retained within the ice-projectile system, what is the mass of ice Δm\Delta m that melts?

44

A spherical ice nanoparticle of radius RR is in phase equilibrium with surrounding liquid water at atmospheric pressure P0P_0. The surface tension of the ice-water interface is γ\gamma. Due to surface reconstruction, the density of ice at the boundary layer (where melting occurs) is ρs\rho_s, which differs from the bulk ice density ρi\rho_i. The density of bulk water is ρw\rho_w. The latent heat of fusion per unit mass is LL, and the normal melting point at P0P_0 is T0T_0. Assuming the temperature shift ΔT≪T0\Delta T \ll T_0, which of the following expressions correctly represents the shift in the melting point ΔT\Delta T of the nanoparticle?

45

A mass mm of a liquid boils and transforms into vapor at a constant temperature TT and pressure PP. The latent heat of vaporization of the liquid is LL. If the slope of the liquid-vapor phase boundary in the pressure-temperature (P−TP-T) diagram at this state is given by dPdT\frac{dP}{dT}, which of the following expressions correctly represents the change in internal energy (ΔU\Delta U) of the system during this complete phase transition?

46

A closed cubical container of side length HH is completely filled with a liquid of total mass MM and density ρ\rho. The container is initially at rest, and the liquid is at its normal boiling point T0T_0 with the pressure at the top-front edge (x=0,y=0x=0, y=0) being P0P_0. The container is then given a constant horizontal acceleration aa in the −x-x direction (where yy is the downward vertical direction). The rate of change of the boiling point with pressure is a constant α\alpha (i.e., dTdP=α\frac{dT}{dP} = \alpha). To maintain the liquid at the verge of boiling everywhere and to vaporize a small uniform mass fraction ff of the liquid throughout the volume, a total heat QQ must be supplied. Assume the pressure at the top-front edge remains P0P_0, and the volume of vapor formed is negligible. Given CC is the specific heat capacity of the liquid and LvL_v is the latent heat of vaporization, find the total heat QQ supplied.

47

Three identical cylindrical rods, each of length LL and cross-sectional area AA, are joined at a common junction JJ to form a star network. The free ends of the rods are maintained at constant temperatures T1=500 KT_1 = 500 \text{ K}, T2=100 KT_2 = 100 \text{ K}, and T3=100 KT_3 = 100 \text{ K}. The thermal conductivity of the material of the rods varies with absolute temperature TT as k=αTk = \alpha T, where α\alpha is a positive constant. Assuming steady-state heat flow and no heat loss from the lateral surfaces of the rods, what is the temperature of the junction JJ?

48

A uniform rod of length LL and cross-sectional area AA is rigidly clamped between two fixed walls at x=0x=0 and x=Lx=L. The Young's modulus of the rod is YY. The thermal conductivity of the rod varies with position as K(x)=K0(1+xL)K(x) = K_0 \left(1 + \frac{x}{L}\right), and the coefficient of linear thermal expansion varies as α(x)=α01+xL\alpha(x) = \frac{\alpha_0}{1 + \frac{x}{L}}. Initially, the entire rod is at a uniform temperature TiT_i. The end at x=0x=0 is maintained at TiT_i, and the end at x=Lx=L is maintained at Ti+T0T_i + T_0. Assuming steady-state heat flow is established and the walls do not yield, what is the thermal stress σ\sigma developed in the rod?

49

Consider a blackbody cavity of volume VV at an equilibrium temperature TT. Due to photon neutrality, the number of photons is not conserved, and their chemical potential is zero. Let EwE_w be the energy of a single photon corresponding to the wavelength λmax\lambda_{max} at which the spectral energy density per unit wavelength is maximum. Let ⟨E⟩\langle E \rangle be the average energy of a photon in the cavity. If xx is the non-zero root of the equation x=5(1−e−x)x = 5(1 - e^{-x}), which of the following expressions correctly represents the ratio Ew⟨E⟩\frac{E_w}{\langle E \rangle}? \ (Given: ∫0∞ys−1ey−1dy=Γ(s)ζ(s)\int_0^\infty \frac{y^{s-1}}{e^y - 1} dy = \Gamma(s)\zeta(s), where ζ(s)\zeta(s) is the Riemann zeta function, Γ(4)=6\Gamma(4)=6, Γ(3)=2\Gamma(3)=2, and ζ(4)=π490\zeta(4)=\frac{\pi^4}{90})

50

A cylindrical rod of length LL and cross-sectional area AA is placed between two heat reservoirs maintained at temperatures T1=800 KT_1 = 800 \text{ K} (at x=0x = 0) and T2=200 KT_2 = 200 \text{ K} (at x=Lx = L). The thermal conductivity of the rod varies with position xx as k(x)=k0(1+xL)2k(x) = k_0 \left(1 + \frac{x}{L}\right)^2, where k0k_0 is a positive constant. The lateral surface of the rod is perfectly insulated. In the steady state, a small hole is made at the midpoint of the rod (x=L/2x = L/2) to observe the emitted blackbody radiation. If Wien's displacement constant is bb, what is the wavelength λmax\lambda_{\text{max}} corresponding to the maximum spectral emissive power of the radiation emitted from the midpoint?

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